Colloidal Quantum Dot Solar Cells: Tailoring Properties from the Suprananocrystalline Level to the Atomic Level
Gerasimos Konstantatos a
a ICFO-Institut de Ciencies Fotoniques, The Barcelona Institute of Science and Technology, Avinguda Carl Friedrich Gauss, 3, Castelldefels, Spain
International Conference on Hybrid and Organic Photovoltaics
Proceedings of 6th International Conference on Hybrid and Organic Photovoltaics (HOPV14)
Ecublens, Switzerland, 2014 May 11th - 14th
Organizers: Michael Graetzel and Mohammad Nazeeruddin
Oral, Gerasimos Konstantatos, presentation 175
Publication date: 1st March 2014

We will discuss recent progress of colloidal quantum dot solar cells focusing on new architectures for efficient CQD solar cells. I will describe the concept of bulk nanoheterojunctions and their employment in PbS-Bi2S3 colloidal nanocrystals. We will show the benfits of this architecture in increasing charge collection efficiencies in the regime of poorly performing materials suffering fast recombination roadblocks.

I will then move on to outline further insights on the underlying mechanisms in these architectural platform. We will demonstrate the critical role of the local environment of the colloidal quantum dots and how this can act as a leverage to passivate trap recombination centers in colloidal quantum dots. This results in transforming the operational behavior of the device from the trap-assisted recombination regime to the band to band recombination regime, enabling therefore the reach of the theoretically predicted open-circuit voltage.

Subsequently I will discuss new doping schemes for colloidal quantum dots and demonstrate their application in robust p-n PbS QD homojunctions. I will conclude with some recent progress on new light trapping schemes for thin film colloidal quantum dot solar cells based on large area soft-imprint nanolithographically made gratings.



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