Efficient and Durable Mixed Halide (CH3NH3PbI3-xClx) Perovskite Solar Cells
Ludmila Cojocaru a, Hiroshi Segawa a, Takaya Kubo a, Satoshi Uchida b, Tsutomu Miyasaka c, Aja Kumar Jena c
a Research Center for Advanced Science and Technology (RCAST), The University of Tokyo, Japan, Japan
b Graduate School of Engineering, Toin University of Yokohama, Kurogane-cho 1614, Aoba-ku, Yokohama, 225-8503
International Conference on Hybrid and Organic Photovoltaics
Proceedings of 6th International Conference on Hybrid and Organic Photovoltaics (HOPV14)
Ecublens, Switzerland, 2014 May 11th - 14th
Organizers: Michael Graetzel and Mohammad Nazeeruddin
Poster, Ludmila Cojocaru, 211
Publication date: 1st March 2014

Organometallic halide perovskite have recently emerged as a new class of excellent light absorbers with carrier-transport function that have demonstrated exceptional progress in solar cells performance. These compounds exhibit very high efficiency using simple planar configurations. We report on the stabilization of a iodide/chloride mixed-halide (CH3NH3PbI3-xClx) perovskite sensitized solid-state solar cells using spiro-OMeTAD as hole transport materials. Our samples of a solution processed planar thin-film architecture (FTO/compact TiO2/perovskite/HTM/Au) achieved a remarkable photovoltaic performance with excellent stability on time.  Interestingly, even when the sample are stored in the air at the room temperature without encapsulation,a long-term stability for over 600 h was observed for the cell with high power conversion efficiency of 12.5 % under standard illumination conditions (100 mW/cm2, AM 1.5G). In order to accomplish high reproducibility and improvement of the short-term performances of the devices we optimized the several issues (such as temperature, pressure, nature of the compact layer, and additives).



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