Effect of Structural Phase Transition on Charge-Carrier Lifetimes and Defects in CH3NH3SnI3 Perovskite
Michael Johnston a, Henry Snaith a, Thomas Stergiopoulos a, Rebecca Milot a, Elizabeth Parrott a, Laura Herz a
a Department of Physics, University of Oxford, Clarendon Laboratory, Parks Road, Oxford OX1 3PU, United Kingdom
International Conference on Hybrid and Organic Photovoltaics
Proceedings of International Conference on Hybrid and Organic Photovoltaics (HOPV16)
Swansea, United Kingdom, 2016 June 29th - July 1st
Organizers: James Durrant, Henry Snaith and David Worsley
Poster, Elizabeth Parrott, 081
Publication date: 28th March 2016

Methylammonium tin triiodide (MASnI3) has been successfully employed in lead-free perovskite solar cells, but overall power-conversion efficiencies are still significantly lower than for lead-based perovskites. The photoluminescence (PL) lifetime for this material is also low, which could be the result of high doping density[1] or the effect of traps caused by defects.[2] We evaluate the optoelectronic properties of MASnI3 as a function of temperature from PL spectra and time-resolved PL to reveal the nature of the phase transitions and the influence of impurities on charge-carrier scattering and recombination life times.  This could be used to optimise the material further and to gain insight into the general optoelectronic properties of organic-metal-halide perovskites. 

 

[1]         N. K. Noel, S. D. Stranks, A. Abate, C. Wehrenfennig, S. Guarnera, A. Haghighirad, A. Sadhanala, G. E. Eperon, S. K. Pathak, M. B. Johnston, A. Petrozza, L. Herz, and H. Snaith, “Lead-Free Organic-Inorganic Tin Halide Perovskites for Photovoltaic Applications,” Energy Environ. Sci., vol. 7, pp. 3061–3068, 2014.

[2]         N. K. Noel, A. Abate, S. D. Stranks, E. S. Parrott, V. M. Burlakov, A. Goriely, and H. J. Snaith, “Enhanced Photoluminescence and Solar Cell Performance via Lewis Base Passivation of Organic À Inorganic Lead Halide Perovskites,” ACS Nano, vol. 8, no. 10, pp. 9815–9821, 2014.



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