Photoinduced Changes at the TiO2 - Perovskite Interface
Ronen Gottesman a, Arie Zaban a, Shay Tirosh a, Jiangang Hu a, Laxman Gouda a
a Bar Ilan University, Bar Ilan University, Ramat Gan, 52900, Israel
International Conference on Hybrid and Organic Photovoltaics
Proceedings of International Conference on Hybrid and Organic Photovoltaics (HOPV16)
Swansea, United Kingdom, 2016 June 29th - July 1st
Organizers: James Durrant, Henry Snaith and David Worsley
Oral, Ronen Gottesman, presentation 089
Publication date: 28th March 2016

CH3NH3PbX3 perovskites have attracted significant attention as absorber materials for solar light harvesting, reaching power conversion efficiencies above 20%. Although there is a prompt evolution of the cell efficiencies, the understanding of basic properties of these semiconductors is still ongoing. Important device operation related questions still need to be answered: the hysteresis behavior, i.e., the difference of the performance between the two voltage directions when performing a current–voltage measurement, and progressively more attention is focused on the role of ions or vacancies migration under an electrical field. The magnitude of the hysteresis seems to be influenced by the n-type interlayer contact, with the most significant observed hysteresis in devices containing TiO2.

We have conducted measurements on perovskite solar cells, comprised of different metal-oxide (MO) electrodes, as the n-type contact. The significance of the selected MO is observed, since the MO – Perovskite interface is affected, especially upon illumination. Under illumination the dielectric constant of the perovskite changes dramatically, thus forming the effect at the MO – Perovskite interface. This effect is mainly influenced by four parameters: the dielectric constant of the MO, the existing electrical field across the interface, the thickness of the MO and the illumination intensity.

 

 

 

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