Selection of Green Solvents of Organic Solar Cells (OPV) Via Binary Solvent Gradient Method
A.M. Cruz a, L. Molina a, M. Della Pirriera a, Pau Bosch a, L. Bautista Pérez b, S. Shankaran b, A. Colsmann b, D. Landerer b, C. Sprau b, V. G. Gregoriou c, C.L. Chochos c
a Leitat Technological Center, Carrer de la Innovació 2, 08225, Terrassa
b Karlsruhe Institute of Technology (KIT), Light Technology Institute, Engesserstrasse 13, Karlsruhe, 76131, Germany
c Advent Technologies SA, Patras Science Park, Stadiou Street, Platani-Rio, 26504, Patra
International Conference on Hybrid and Organic Photovoltaics
Proceedings of International Conference on Hybrid and Organic Photovoltaics (HOPV16)
Swansea, United Kingdom, 2016 June 29th - July 1st
Organizers: James Durrant, Henry Snaith and David Worsley
Poster, Pau Bosch, 198
Publication date: 28th March 2016

Organic photovoltaic cells show tremendous promise as energy conversion devices, thanks to key attributes such as flexibility and low-cost production. The field of organic electronics is entering its commercial phase. The recent market introduction of the first prototypes based on organic electronic components, as organics transistors is set to augment the existing market presence for other technologies and organic photovoltaic products are not far behind. A possible insertion of the OPV technology in the market involves a safe and environmentally friendly production process. However, the toxicity of these solvents will not allow proceeding to mass production in industrial countries with a strict environmental, health and safety (EHS) legislation. In addition organic solar cells based in chlorinated solvents are not suitable for large-area fabrication since the safety precautions for large-area deposition in an industrial environment would increase the production cost beyond any economical sensible measure. In this work we focus on the binary solvent gradient method to calculate Hansen solubility parameters (HSP) for the design of green ink formulations of polymer/fullerene bulk-heterojunction for solar cells. A list of suitable green solvents was obtained from a computer simulation using the HSP of both polymers and the junction. Thin films and devices were fabricated in order to validate experimentally the theoretical results. The efficiencies were compared with the performance of devices fabricated from common halogenated solvents. The aim of this work is to use a new approach to calculate HSP with less experimental effort and polymer/fullerene blends. The choice of solvents is a critical aspect that affects conformation and distribution of the molecules in OPV inks. The use of non-conventional solvents for OPV fabrication is not only an opportunity to reduce health and environmental hazards during the process. As the list of possible solvents is extensive (nowadays we are working with 22.000 solvents), a suitable method must be selected in order to reduce the amount of solvent under proposed criteria.
 

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