Degradation Studies of Organometal-Halide Perovskite
Paul E. Hopkinson a, David Becker-Koch a, Yana Vaynzof a, Paul Fassl a, Qing Sun a
a Kirchhoff-Institute for Physics, Ruprecht-Karls-University Heidelberg, Im Neuenheimer Feld, 227, Heidelberg, Germany
b Center for Advanced Materials, Ruprecht-Karls-University Heidelberg, Im Neuenheimer Feld, 225, Heidelberg, Germany
International Conference on Hybrid and Organic Photovoltaics
Proceedings of International Conference on Hybrid and Organic Photovoltaics (HOPV16)
Swansea, United Kingdom, 2016 June 29th - July 1st
Organizers: James Durrant, Henry Snaith and David Worsley
Poster, Qing Sun, 259
Publication date: 28th March 2016

The last five years have witnessed a remarkable increase in the power conversion efficiency of hybrid organometal-halide perovskite solar cells reaching 22% to date. However, the low environmental stability of the devices has not been thoroughly investigated and remains only partly understood.

Currently, we are studying pristine and degraded perovskite films with a broad range of measurement methods in order to understand the dynamics and the underlying physical principles of the degradation under controlled exposure to oxygen, water as well as light. The solution processed perovskite films are first degraded under controlled conditions with our environmental stability testing rig and then characterized by multiple techniques such as XPS, UPS, PDS, PL and SEM. These results are then correlated to the degradation of complete photovoltaic devices under identical conditions. First results obtained on methylammonium lead iodide (CH3NH3PbI3) films and hole conductor free solar cells show that exposure to oxygen, and not only water, plays an important role in the degradation of perovskite solar cells.



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