Highly efficient small molecule organic solar cells using halogen-free solvent
Jegadesan Subbiah a, Paul Geraghty a, David Jones a
a School of Chemistry, Bio21 Institute, University of Melbourne, Australia., Parkville Victoria 3010, Australia, Parkville, Australia
International Conference on Hybrid and Organic Photovoltaics
Proceedings of International Conference on Hybrid and Organic Photovoltaics (HOPV18)
Benidorm, Spain, 2018 May 28th - 31st
Organizers: Emilio Palomares and Rene Janssen
Poster, Jegadesan Subbiah, 257
Publication date: 21st February 2018

In recent years, significant progress in organic semiconducting materials development and device engineering has boosted the power conversion efficiency of organic photovoltaic (OPV) devices up to the commercialization threshold. However, the bulk-heterojunction active layer film forming process for high performance organic solar cells mostly achieved by halogenated solvents such as chloroform, chlorobenzene, or o-dichlorobenzene, which is harmful to health and environment. Hence, it is mandatory to develop environmental friendly solvent processing technology for greener, cheaper and large area OPV device fabrication. Recently, we have reported new molecular materials (BQR) with OPV device efficiency of 9.4% using halogenated solvent (chloroform) along with fullerene acceptor. Here, we have studied the performance of BQR with various halogen-free solvents (toluene, xylene, mesitylene etc.,) and the OPV device processed with toluene exhibits the best device performance of 10.8% with a high fill factor of 77%. The halogen-free solvent improves active layer film formation and nanoscale morphology comparing to the halogenated solvent. We have also explored the device performance and characterisation with various anode interlayers including metal oxides, towards the fabrication efficient and air-stable devices.

 

 

 

© FUNDACIO DE LA COMUNITAT VALENCIANA SCITO
We use our own and third party cookies for analysing and measuring usage of our website to improve our services. If you continue browsing, we consider accepting its use. You can check our Cookies Policy in which you will also find how to configure your web browser for the use of cookies. More info