Perovskite solar cells on steel substrates: Optimization of a dielectric/metal/dielectric transparent top electrode
Benjamin Feleki a, Ricardo Bouwer b, Sanjana Chandrashekar b, Martijn M. Wienk a c, René A.J. Janssen a c
a Molecular Materials and Nanosystems, Eindhoven University of Technology, Netherlands, Netherlands
b TATA Steel, Research and Development, Surface Engineering – Coating development, IJmuiden, The Netherlands
c Dutch Polymer Institute (DPI), P.O. Box 902, Eindhoven, 5600 AX, Netherlands
International Conference on Hybrid and Organic Photovoltaics
Proceedings of International Conference on Hybrid and Organic Photovoltaics (HOPV18)
Benidorm, Spain, 2018 May 28th - 31st
Organizers: Emilio Palomares and Rene Janssen
Poster, Benjamin Feleki, 273
Publication date: 21st February 2018

Lead-based perovskite solar cells (PSCs) have exceeded power conversion efficiencies (PCEs) over 22%. In order to fabricate PSCs on flexible substrates, the substrate needs to endure several fabrication related conditions (high temperature, corrosion and flexibility). Coated steel substrate is a suitable candidate to overcome these challenges and desirable for building integrated photovoltaics.

Here we present the development of a PSC fabricated in the following sequence: coated steel substrate/gold bottom electrode/SnO2/PCBM/perovskite/spiro-OMeTAD/MoO3/gold/polystyrene. The dielectric/metal/dielectric top electrode stack was optimized using optical simulation and tested both on semitransparent and gold metal bottom electrode device architectures. By employing polystyrene as the top dielectric in the top electrode stack, the light incoupling can be greatly enhanced enabling PCEs up to 11.4% for PSCs on coated steel substrate. Our optical loss analysis highlighted that the generated photocurrent of these PSCs is mainly limited by the parasitic light absorption originating from the hole transport material and the transparent top electrode stack.

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