Materials Innovation and Interfacial Engineering for Practical Perovskite Photovoltaics: From Molecular Design to Commercialization
Atsushi Wakamiya a,  b
a Institute for Chemical Research, Kyoto University
b EneCoat Technologies, Co. Ltd.
Keynote, Atsushi Wakamiya, presentation 009
Publication date: 22nd October 2026

Perovskite solar cells (PSCs) have attracted widespread attention as promising next-generation photovoltaics due to their high power conversion efficiency and low-cost solution processability. Over the past decade, we have advanced both fundamental and applied research in this field from the perspective of materials chemistry, aiming to achieve high device performance together with commercial viability. In 2018, based on our academic achievements, we established the Kyoto University spin-off startup, EneCoat Technologies Co., Ltd., to accelerate the practical application of perovskite solar modules.

Our research strategy focuses on rational molecular design to control charge collection, surface passivation, and energy-level alignment at the device interfaces:

1) Novel Charge-Collecting Materials: We have designed and synthesized novel multipodal pi-conjugated materials, such as PATAT-based compounds, to optimize frontier orbital levels, molecular orientation, and charge transport properties.1-3) Furthermore, as new charge-collecting options, we have recently developed two-dimensionally extended sheet-type materials incorporating pi-conjugated systems linked via ene-thiol chemistry or boroxine cores.

2) Interfacial and Surface Modification: Based on a "dipole strategy," we have developed functional organic passivating materials that modify both the top and bottom surfaces of the perovskite layer, suppressing non-radiative recombination and dramatically improving carrier extraction.4-7)

These material innovations have enabled significant performance enhancements across single junction cells, large-area modules, and all-perovskite tandem architectures.8-12) In this presentation, I will report on our recent research progress, with a particular focus on novel two-dimensionally extended interfacial materials and their impact on device efficiency and stability. Additionally, I will briefly introduce our manufacturing efforts for perovskite solar cells at EneCoat Technologies, following the recent completion of our new headquarters and factory facility.

The author thank many collaborators and students, Dr. T. Nakamura, Dr. M. A. Truong, C.-Y. Chen, Dr. R. Murdey, Dr. S. Hu, Dr. Y. Kanemitsu, in Kyoto University, etc. This work was supported by the New Energy and Industrial Technology Development Organization (NEDO) (JPNP25011), NEDO-GI (JPNP21016), JST–MIRAI (JPMJMI22E2), and JST PRESTO (JPMJPR25H6), International Collaborative Research Program of ICR (Kyoto University), ICR Grants for Promoting Integrated Research (Kyoto University), Grants for the Integrated Research Consortium on Chemical Sciences, Grant-in-Aid for Scientific Research (A) (JP24H00481, JP24H00446), and Grant-in-Aid for Scientific Research (B) (JP24K01571, JP24K01607).

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