Proceedings of Asia-Pacific International Conference on Perovskite, Organic Photovoltaics and Optoelectronics (IPEROP27)
Publication date: 22nd October 2026
Solar energy is a clean and abundant renewable energy source, but its use is affected by changes in sunlight. Photoelectrochemical (PEC) technology can convert solar energy into hydrogen for energy storage. However, the oxygen evolution reaction (OER) in conventional water splitting involves a complex four-electron transfer process, which requires a high overpotential and has slow reaction kinetics. These limitations increase the overall operating voltage and reduce solar energy conversion efficiency.¹
In this study, the ascorbic acid oxidation reaction (AAOR) was used to replace OER and reduce the required anodic potential. AAOR was coupled with the hydrogen evolution reaction (HER) to develop a bias-free PEC hydrogen production system. The catalytic activity of different catalysts toward AAOR was studied, and a solar cell was combined with a commercial Pt/C catalyst to form a monolithic photocathode. Compared with conventional OER, AAOR can occur at a lower oxidation potential and convert ascorbic acid into the valuable product dehydroascorbic acid (DHA) through a two-electron oxidation reaction.²
The developed PEC system achieved a hydrogen Faradaic efficiency (FE) of over 90% and a DHA selectivity of over 90%. These results show that combining AAOR with HER can produce hydrogen and valuable chemicals at the same time without external electrical bias. This approach provides a promising way to reduce the energy required for PEC hydrogen production while using solar energy to produce valuable chemicals.
