Zwitterionic Ligand-Induced Faster Decay of FAPbI₃ Quantum Dots
Yoju choi a, Nurwarrohman Andre Sasongko a, Myeongkee Park a
a BB21+, Department of Chemistry, Pukyong National University, Busan, 48513, Korea
Poster, Yoju choi, 108
Publication date: 22nd October 2026

Formamidinium lead iodide (FAPbI3) perovskites are promising absorbers for lightweight, radiation-tolerant space photovoltaics. In addition, controlling the shape and surface of their quantum dots (QDs) offers a route to tailoring their optical properties. In conventional hot-injection synthesis, oleylammonium preferentially stabilizes the nonpolar {100} facets, yielding cube-shaped QDs, whereas facets rich in undercoordinated Pb2+ are rarely exposed. Here, the zwitterionic ligand 3-(decyldimethylammonio)propanesulfonate (DPSI) can be used to control the facet growth of FAPbI₃ QDs by passivating undercoordinated Pb2+ through its sulfonate group. DPSI was heat-treated with PbI2 before oleic acid and oleylamine were injected. Transmission electron microscopy (TEM) showed that pristine FAPbI3 QDs had a uniform cubic morphology, whereas non-cubic morphologies were also observed in DPSI-FAPbI₃ QDs. X-ray diffraction revealed additional (012) reflections and a  broader (001) peak, with no detectable δ-phase. Both the absorption and photoluminescence (PL) spectra of DPSI-FAPbI3 QDs were blue-shifted relative to those of pristine QDs. The PL quantum yield remained comparable to that of pristine QDs (51% vs. 56%), whereas the average PL lifetime decreased from 72 to 29 ns, corresponding to 2.5-fold increase. We attribute this to stronger carrier confinement in the (012)-faceted QDs, which increases both electron–hole overlap and carrier access to surface sites. These results indicate that zwitterionic ligands can be used to tune the morphology and radiative dynamics of FAPbI3 QDs.

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