Proceedings of Asia-Pacific International Conference on Perovskite, Organic Photovoltaics and Optoelectronics (IPEROP27)
Publication date: 22nd October 2026
Surfaces govern the structural, electronic and chemical properties of colloidal semiconductor nanocrystals (NCs), forming a dynamic boundary between the confined electron and hole wavefunctions of the inorganic core and the surrounding medium. Lead halide perovskite (LHP) NCs are especially sensitive to this boundary: their low lattice formation energies and high ionicity cause labile ligand binding and easy structural and morphological transformations. In this poster, we survey strategies toward an ideal ligand shell for LHP NCs, including ligand-binding dynamics, cationic and zwitterionic ligands, emerging anionic capping, and techniques for characterizing the ligand shell. We also introduce charge-extracting ligands, which can enable efficient interfacial charge transfer in place of insulating long-chain capping layers. Beyond the binding group, ligand tails set colloidal stability, interparticle spacing and interactions with the surrounding matrix, which makes them a tunable design element in their own right. We find that no ligand is universally ideal: binding affinity, exchange kinetics, geometric fit and tail interactions must be matched to the intended application, whether classical or quantum light sources or photocatalysis.
