Photo-Rechargeable Zinc-Ion Capacitor Based on Rhenium- and Niobium-doped Tungsten Diselenide
Monaam Benali a, Zdenek Sofer a
a University of Chemistry and Technology, Prague, Technická 5, Praha 6, Prague, Czech Republic
Materials for Sustainable Development Conference (MATSUS)
Proceedings of MATSUS Spring 2024 Conference (MATSUS24)
#PhotoMat - Advances in Photo-driven Energy Conversion and Storage: From Nanoscale Materials to Sustainable Solutions
Barcelona, Spain, 2024 March 4th - 8th
Organizers: Michelle Browne, Bahareh Khezri and Katherine Villa
Oral, Monaam Benali, presentation 050
DOI: https://doi.org/10.29363/nanoge.matsus.2024.050
Publication date: 18th December 2023

Simultaneously harvesting, converting and storing solar energy in a single device represents an appealing technological approach for the next generation of power sources. Herein, we propose a device consisting of a single piece of (rhenium, Re; niobium, Nb) doped WSe2 photocathode and zinc foil anode system capable of harvesting solar energy (and converting it into electricity) and a rechargeable aqueous zinc metal cell. The proposed cell demonstrated an improvement in the specific capacitance of around 45% under visible light irradiation. Also, Re doped WSe2 exhibited a loss of 4.44 % at its initial specific capacitance after 500 galvanostatic charge-discharge cycles at 50 mA g-1. As a result, the device delivered a specific energy density of 574.21 mWh Kg-1 at a power density of 5906 mW Kg-1 and at 0.015A g-1. Furthermore, the notable enhancement in capacitance achieved through the Re-WSe2 photo-zinc ion capacitor (photo-ZIC) offers a straightforward and constructive avenue to establish a cost-effective and highly efficient solar-electrochemical capacitor system.

The research leading to these results was supported by the the Johannes Amos Comenius Programme, European Structural and Investment Funds, project 'CHEMFELLS V‘ (No. CZ.02.01.01/00/22_010/0003004).

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