Green Horizons: Advancing Sustainable Perovskite Solar Technologies Through Innovative Halide Chemistry and Eco-Friendly Production Practices
Senol Öz a, Tim Ludwig a, Christoph Bohr a, Robert Frohnhoven a, Shahaboddin Resalati b, Amani Maalouf b, Tobechi Okoroafor b
a Solaveni GmbH, Germany
b Oxford Brookes University, Oxford OX3 0BP, United Kingdom
Materials for Sustainable Development Conference (MATSUS)
Proceedings of MATSUS Spring 2024 Conference (MATSUS24)
#SusPer - Sustainability of halide perovskites
Barcelona, Spain, 2024 March 4th - 8th
Organizers: Francesca Brunetti and Iris Visoly-Fisher
Invited Speaker, Senol Öz, presentation 121
DOI: https://doi.org/10.29363/nanoge.matsus.2024.121
Publication date: 18th December 2023

Perovskite solar technology has rapidly demonstrated its commercial potential within just over ten years of intense research efforts worldwide. Its remarkable attributes, including high specific power, cost-effective production, and superior performance in low-light conditions, have significantly enhanced its value across various applications, distinguishing it from other photovoltaic technologies. Hybrid organic-inorganic perovskites merge the benefits from both realms: the ease of solution processing inherent in organic small molecules or polymeric semiconductors, as seen in organic polymer solar cells, and the exceptional physical characteristics of high-performance (poly or single)-crystalline inorganic semiconductors. This fusion creates a single material class that encompasses the advantages of both.

Sustainable, safe and industry compatible processing routes are paramount to enable large scale production of perovskite photovoltaics. Green and sustainable perovskite photovoltaics are not only enabled by the choice of processing, but sustainability starts already at the material level!

Sustainable perovskite precursor synthesis is enabled by novel and innovative green halide chemistry developed by Solaveni in Germany.[1] In this talk, the advantages of the novel synthesis routes for organic alkylammonium halides as well as metal halides (PbX2, SnX2; X= halide) are highlighted and benchmarked from an LCA perspective against the conventional production routes. The LCA analysis delves into the specific environmental impacts of these precursor materials, assessing factors such as resource consumption, energy use, and emissions, offering critical insights into their sustainability profiles and contributing to the overall understanding of the ecological footprint associated with such materials.

Furthermore, we present the latest developments in lead-free tin halide perovskite solar modules obtained via industry compatible coating techniques using Solaveni’s custom made SnI2 inks.[2]

This project received funding from the European Union’s Horizon Europe research and innovation program under grant agreement no. 101122345 (Project HEPAFLEX).

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