Recycling of LiNiyMnzCoxO2 from cathode of discarded lithium-ion batteries using relithiation process
Lucas Sita b, Rob Sommerville a, Jair Scarminio b, Emma Kendrick a
a School of Metallurgy and Materials, University of Birmingham, Edgbaston Park Road, United Kingdom
b Londrina State University, Brazil
Materials for Sustainable Development Conference (MATSUS)
Proceedings of MATSUS Spring 2024 Conference (MATSUS24)
#CircularMat - Circular Economy for Sustainable Energy Materials
Barcelona, Spain, 2024 March 4th - 8th
Organizers: Susana Iglesias Porras, BENING TIRTA MUHAMMAD and Matthew Royle
Oral, Lucas Sita, presentation 286
DOI: https://doi.org/10.29363/nanoge.matsus.2024.286
Publication date: 18th December 2023

Recycling processes for lithium-ion batteries (LIBs) have been developed to remove chemical compounds from these batteries for secondary uses, as well as resynthesizing cathode material using direct or short-loop recycling, for use in cathodes of fresh batteries. The reason for extracting compounds from the cathode of discarded LIBs is that they are composed of high value and critical minerals such as Li, Co, Ni and Mn. In particular the cathodes with compositions such as LiCoO2, LiNiyMnzCoxO2, and LiMn2O4 are important to evaluate for reclamation of these metals and re-use. It is known from the literature that end-of-life LiNiyMnzCoxO2 contains around 15 to 20% less lithium than fresh cathode and therefore cannot be directly reuse without further lithiation. It is a challenge to return this end of life and recovered black mass, containing NMC materials to form that can be reused in a new cell. In this work we describe a direct recycling route for the discarded NMC532 using a low cost, and facile relithiation process. The cathode material was extracted from a disassembled end of life or scrap NMC vs graphite pouch cell, and then delaminated from aluminium using a 3.5M NaOH solution that selectively dissolved the Al foil. The recovered powder was analyzed by XRF, XRD, CHNS and ICP-OES techniques. After characterization, solid state relithiation was carried out with the lithium source LiOH at 700 °C and the product of this reaction was analyzed again using the above techniques and evaluated electrochemically.

Lucas is thankful to CNPq for their PhD scholarship in Brazil, CAPES and the PDSE program for the scholarship granted for the internship at the University of Birmingham. 

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