Modification of Perovskite Active Layer by Co-Evaporation with a Small Organic Molecule
Elena Siliavka a b, Yana Vaynzof a b
a Professur für Neuartige Elektronik Technologien, Technische Universität Dresden, Nöthnitzer Str. 61, 01187, Dresden, Germany.
b Leibniz-Institut für Festkörper- und Werkstoffforschung Dresden (IFW), Helmholtzstraße 20, 01069, Dresden, Germany.
Materials for Sustainable Development Conference (MATSUS)
Proceedings of MATSUS Spring 2024 Conference (MATSUS24)
#PerFut24 - The Future of Metal Halide Perovskites: Fundamental Approaches and Technological Challenges
Barcelona, Spain, 2024 March 4th - 8th
Organizers: Annalisa Bruno, Iván Mora-Seró and Pablo P. Boix
Poster, Elena Siliavka, 517
Publication date: 18th December 2023

Metal halide perovskites are a well-known family of solar cell materials. Despite their remarkable photovoltaic capabilities, there are a number of major obstacles in the field of metal halide perovskite solar cells (PSCs). These include limited light absorption at the edge of the infrared spectrum. One approach to address them is to modify the active layer by doping or even creating complex composites, which is common for the production of PSCs by solution-processed methods, but less so for the thermal evaporation method. However, thermal evaporation allows solubility problems to be solved as well as homogeneous distribution of the additive.

In this study, we focused on the modification of the perovskite layer. A composite consisting of a small organic molecule with near-infrared absorption (BDP-OMe) and perovskite (FA1-xCsxPbI3-xBrx) was deposited by thermal co-evaporation.

The composite formation was confirmed by UVvis, UPS, XPS methods. The presence of BDP-OMe broadens the absorption of composite. It was also shown that the composite formation does not disturb the perovskite crystal lattice.

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