Formation, crystallization and thermal stability of two-dimensional perovskites and their interfaces
Ana Flavia Nogueira a, Murillo Rodrigues a, André Fonseca a
a Laboratório de Nanotecnologia e Energia Solar, University of Campinas (UNICAMP), Chemistry Institute, Campinas, PO Box 6154, 13083-970, Brazil
Proceedings of MATSUS Fall 2025 Conference (MATSUSFall25)
A1 Halide Perovskites - Properties, Synthesis and Advanced Characterization - #PeroProp
València, Spain, 2025 October 20th - 24th
Organizers: Kunal Datta and Selina Olthof
Invited Speaker, Ana Flavia Nogueira, presentation 486
Publication date: 21st July 2025

Metal halide perovskite solar cells have recently achieved an efficiency breakthrough of 26.7%, surpassing that of monocrystalline silicon photovoltaics. This remarkable result was only possible due to precise control and engineering of morphology, interfaces, defects, the use of multiple cations at the perovskite A-site, such as Cs⁺, MA⁺ (methylammonium), FA⁺ (formamidinium), and the incorporation of additives to enhance crystallization, among other strategies.

The dimensionality of perovskite materials can be readily tuned by selecting appropriate A-site cations and adjusting the stoichiometry, enabling the formation of structures ranging from zero-dimensional (0D), one-dimensional (1D), two-dimensional (2D), to three-dimensional (3D). This tunability broadens the applicability of perovskites in a wide range of optoelectronic devices.

In this presentation, we summarize key results obtained through in situ experiments that probe the formation dynamics and crystallization of 2D perovskite materials incorporating various organic cations, along with their stability profiles. The dynamics of structure and interface formation in solution or solid state, and their thermal stability and aggregation behavior were investigated via in situ techniques. These included time-resolved grazing incidence wide-angle X-ray scattering (GIWAXS), high-resolution XRD, in situ TEM, and in situ photoluminescence (PL) spectroscopy, conducted at the Brazilian Synchrotron Light Laboratory, Lawrence Berkeley National Laboratory, and other research facilities.

Additionally, we present our most recent findings on the spatial mapping of 2D nanostructures using cathodoluminescence coupled with scanning electron microscopy (SEM), as well as the role of organic cation chain length in crystallization dynamics, defect passivation, and carrier transport. These properties were probed using advanced characterization techniques such as nanoscale X-ray diffraction and AFM-based infrared spectroscopy.

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