Luminescent Copper-Doped Semiconductor Nanocrystals
Kathryn Knowles a, Heidi Nelson, Patrick Whitham, Troy Kilburn, Arianna Marchioro, Daniel Gamelin
a University of Washington, US, Seattle, United States
Materials for Sustainable Development Conference (MATSUS)
Proceedings of nanoGe September Meeting 2015 (NFM15)
Santiago de Compostela, Spain, 2015 September 6th - 15th
Oral, Kathryn Knowles, presentation 017
Publication date: 8th June 2015

Copper-doped semiconductors are classic phosphor materials that have been used in a variety of applications for nearly a century. Recently, attention has turned to the development of colloidal copper-doped semiconductor nanocrystals, which combine the unique luminescence properties of copper-doped semiconductors with the solubility and optoelectronic tunability of semiconductor nanocrystals. Similar to their bulk counterparts, photoluminescence (PL) in copper-doped semiconductor nanocrystals originates from a charge transfer transition involving an electron in the condution band and a (formally) Cu2+ ion that is generated upon trapping of the photogenerated hole by a Cu+ dopant. This recombination mechanism results in a broad PL spectrum that is significantly lower in energy than the semiconductor band gap, and tunable by varying the size and composition of the nanocrystal. This tunability, combined with the minimal overlap of their absorption and PL spectra, makes copper-doped semiconductor nanocrystals attractive phosphors for numerous applications in optical imaging and spectral conversion. To optimize these materials as phosphors, it is important to understand their electronic structures and photophysical properties in detail. This talk will present data from a combination of optical and magnetooptical measurements and electronic structure calculations investigating the spectroscopic properties of copper-doped semiconductor nanocrystals. These data elucidate details of the electronic structures of these materials, with particular focus on the properties of the luminescent excited state in various copper-doped lattices. 



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