The Bulk Photovoltaic Effect in the Crystal without Center of Symmetry and Solar Harvesting
Vladimir M Fridkin a
a Institute of Crystallography of Russian Academy of Sciences (Moscow), -, Russian Federation
b Physical Department of Drexel University (Philadelphia), -, United States
Materials for Sustainable Development Conference (MATSUS)
Proceedings of September Meeting 2016 (NFM16)
Berlin, Germany, 2016 September 5th - 13th
Organizers: Marin Alexe, Enrique Cánovas, Celso de Mello Donega, Ivan Infante, Thomas Kirchartz, Maksym Kovalenko, Federico Rosei, Lukas Schmidt-Mende, Laurens Siebbeles, Peter Strasser, Teodor K Todorov, Roel van de Krol and Ulrike Woggon
Invited Speaker, Vladimir M Fridkin, presentation 504
Publication date: 14th June 2016

       The Bulk Photovoltaic Effect in the Noncentrosymmetric Crystals (BPE) was experimentally discovered in 1970 [1] and phenomenologically explained in [2, 3]. The BPE is connected with two microscopic mechanisms: ballistic [2, 3] and shift [4, 5]. In spite of high voltage, generated by BPE, wich could exceed energy gap, the energy conversion efficiency (ECE) of BPE in the bulk crystals is extremely small(10-5 -10-6)%. It was recently shown, that at the nanoscale the ECE of this effect is increased by many orders of value [6]. In [7] was shown, that the BPE in pin regime is largely increased.

        In the present talk we give the review of main properties and theory of BPE and consider the possibilities of its application in solar harvesting, wich are revealed at the last time.

                                                                    References

1. A.A. Grekov, M.A. Malitskaya, V.D. Spitsina, and V.M. Fidkin, Sov. Phys. Crystallogr. 15, 423 (1970)

2. A.M. Glass, D. von der Linde, and T.J. Negran, Appl. Phys. Lett. 25, 233 (1974)

3. B.I. Sturman, and V.M. Fridkin, Photovoltaic and Photorefractive Effects in Noncentrosymmetric Materials (Gordon and Breach, Philadelphia, 1992)

4. S.M. Young, and A.M. Rappe, Phys. Rev. Lett. 109, 116601 (2012)

5. S.M. Young, F. Zheng, and A.M. Rappe, Phys. Rev. Lett. 109, 236601 (2012)

6. A. Zenkevich, Yu Matveyev, K. Maksimova, R.Gaynutdinov, A. Tolstikhina, and V. Fridkin Phys. Rev. B90, 161409® (2014)

7. M. Alexe and D. Hesse, Nat. Commun. 2, 256 (2011)

 

 



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