Local Heterogeneity and Radiative Efficiency in Hybrid Perovskite Thin Films
Dane deQuilettes a
a University of Washington, US, Seattle, United States
Materials for Sustainable Development Conference (MATSUS)
Proceedings of September Meeting 2016 (NFM16)
Berlin, Germany, 2016 September 5th - 13th
Organizers: Marin Alexe, Enrique Cánovas, Celso de Mello Donega, Ivan Infante, Thomas Kirchartz, Maksym Kovalenko, Federico Rosei, Lukas Schmidt-Mende, Laurens Siebbeles, Peter Strasser, Teodor K Todorov, Roel van de Krol and Ulrike Woggon
Oral, Dane deQuilettes, presentation 203
Publication date: 14th June 2016

Organic/inorganic hybrid perovskite thin films are promising materials for photovoltaic applications that exhibit significant heterogeneity in local non-radiative recombination rates. In this talk, we will describe both confocal fluorescence lifetime imaging microscopy and scanning-probe microscopy studies that help elucidate the origins of this local heterogeneity in terms of composition and surface defects. We measure local photoluminescence, local electroluminescence, local conductivity via conductive atomic force microscopy, and local surface potential using scanning kelvin probe microscopy (SKPM) and show correlation between these properties and film processing methods.  We further show how specific processing additives and illumination serve to alter the distribution of surfaces states, and demonstrate the “photo-cleaning” effects in perovskite are associated with photo-induced ion motion using time-of-flight mass spectrometry. By using different processing methods and additives, we tailor the materials properties, and we show that we are able to obtain carrier lifetimes and PL intensities in thin films approaching those in single crystals, opening the way for these materials to approach the Shockley-Queisser limit.



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