Photo-catalytic carbon dioxide reduction with InGaN photo-electrodes
Andreas Zeidler a, Viktoria Kunzelmann a, Martin Stutzmann a
Materials for Sustainable Development Conference (MATSUS)
Proceedings of nanoGe September Meeting 2017 (NFM17)
SF1: Material and Device Innovations for the Practical Implementation of Solar Fuels (SolarFuel17)
Barcelona, Spain, 2017 September 4th - 9th
Organizers: Wilson Smith and Ki Tae Nam
Oral, Andreas Zeidler, presentation 062
Publication date: 20th June 2016

Photo-catalytic carbon dioxide (CO2) reduction is one of the most promising prospects for energy storage. The possibility to reduce the content of CO2 in the atmosphere by photo-catalytic CO2 conversion into solar fuels intensifies the interest to investigate this topic even more. Yet, many different issues have to be coped with before CO2 reduction can take a major role in future energy technology. One is the challenge to influence the CO2 reduction process in order to increase the amount of desired products. The use of indium gallium nitride (InGaN) as a working electrode may solve this issue. By adjusting the alloy composition of InGaN, it is possible to tune the band level energies, which might enhance the production of specific products, such as ethanol. In addition to this, InGaN is relatively stable under working conditions and is able to provide high-energy electrons, necessary for CO2 reduction.

The focus of the current work is the fabrication and characterization of such InGaN photo-electrodes. Using plasma-assisted Molecular Beam Epitaxy, we are able to precisely control the n- and p-type doping and alloy composition of the grown InGaN. To investigate the crystal quality of these samples we use High Resolution X-ray Diffraction and low temperature Photoluminescence, which provides information about the defects and in addition delivers the band gap energy. Kelvin Force Probe Microscopy offers interesting information about the surface potential landscape of the samples under illumination and Hall measurements reveal their charge carrier density. By using Cyclic Voltammetry and Impedance Spectroscopy, we are able to get insight into the charge transfer processes between the InGaN electrodes and suitable electrolytes.

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