Material Design for Synaptic Transistors: From Conjugated Polymers to Two-Dimensional Perovskites
Chu-Chen Chueh a
a Department of Chemical Engineering National Taiwan University, TW
Proceedings of Neuronics Conference 2025 (Neuronics25)
Tsukuba, Japan, 2025 June 17th - 20th
Organizers: Takashi Tsuchiya, Chu-Chen Chueh, Sabina Spiga and Jung-Yao Chen
Invited Speaker, Chu-Chen Chueh, presentation 051
Publication date: 15th April 2025

Our research group focuses on the development of functional polymers and hybrid perovskites in various optoelectronic devices, including thin-film transistor (TFT), (photo-)memory, light-emitting diode (LED), and solar cell devices. We particularly focus on the relationship between the structure and properties of polymers and perovskites. In addition to advances in the controlled synthesis of these solution-processable semiconductors, we also explore innovative interface and device engineering to optimize device performance. In this presentation, we will share our recent works on the design of conjugated polymers and Sn-based 2D perovskites for transistor memories, and extend this to synaptic transistors. We will first discuss the design of organic materials for dielectric and active layers to realize organic synaptic transistors, followed by their device applications and optimization. Finally, we will highlight the potential of 2D Sn-based perovskites in memory and synaptic applications.

 

References:

[1] Q. G. Chen, W. T. Liao, R. Y. Li, I. Sanjuan, N. C. Hsiao, C. T. Ng, T. T. Chang, A. Guerrero, C. C. Chueh*, W. Y. Lee*, “Organic Solid-State Electrolyte Synaptic Transistors with Photoinduced Thiol-Ene Cross-linked Polymer Electrolytes for Deep Neural Networks”, ACS Mater. Lett., 2025, 7, 682-691.

[2] Y. T. Yang, Y. H. Shih, C. H. Chen, Q. G. Chen, M. H. Yu, B. H. Lin, W. C. Chen, W. Y. Lee*, C. C. Chueh*, “Revealing the Potential of Perovskite Transistors for Dual-modulated Synaptic Behavior through Heterojunction Design”, ACS Energy Lett. 2024, 9, 4564-4571.

[3] I. H. Chao, Y. T. Yang, M. H. Yu, C. H. Chen, C. H. Liao, B. H. Lin, I. C. Ni, W. C. Chen, A. W. Y. Ho-Baillie, C. C. Chueh*, “Performance Enhancement of Lead-Free 2D Tin Halide Perovskite Transistors by Surface Passivation and Its Impact on Non-Volatile Photomemory Characteristics”, Small, 2023, 19, 2207734.

[4] Y. T. Yang, Y. S. Wu, W. He, H. C. Tien, W. C. Yang, T. Michinobu, W. C. Chen, W. Y. Lee*, C. C. Chueh*, “Tuning Ambipolarity of the Conjugated Polymer Channel Layers of Floating-Gate Free Transistors: From Volatile Memories to Artificial Synapses”, Adv. Sci. 2022, 9, 2203025.

[5] T. F. Yu, H. Y. Chen, M. Y. Liao, T. T. Chang, C. C. Chueh*, W. Y. Lee*, “Solution-Processable Anion-Doped Conjugated Polymer for Nonvolatile Organic Transistor Memory with Synaptic Behaviors”, ACS Appl. Mater. Interfaces. 2020, 12, 33968-33978.

[6] https://chuehslab2016.wixsite.com/ccchueh

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