Extending the Range of Useful Polymers in NFA-based Solar Cells Using a Ternary Solvent System
Tom P.A. van der Pol a, Martijn M. Wienk a, René A.J. Janssen a
a Molecular Materials and Nanosystems, Eindhoven University of Technology, Netherlands, Netherlands
International Conference on Hybrid and Organic Photovoltaics
Proceedings of Online International Conference on Hybrid and Organic Photovoltaics (OnlineHOPV20)
Online, Spain, 2020 May 26th - 29th
Organizers: Tracey Clarke, James Durrant, Annamaria Petrozza and Trystan Watson
Poster, Tom P.A. van der Pol, 043
Publication date: 22nd May 2020
ePoster: 

The world of organic solar cells (OSC) have been taken by storm by the recent developments in non-fullerene acceptors (NFAs) with record efficiencies being published in close succession. However, not all polymers that previously performed well in fullerene based devices are suitable for use in a blend with NFAs. This seems to be especially the case for diketopyrrolopyrrole (DPP) based polymers and currently there is a lack of understanding as to why. In our research we aim to improve on solar cell performance of DPP-NFA blends and elucidate the reason behind their suboptimal performance in order to extend the range of useful polymers in high efficiency (near infra-red absorbing) NFA OSCs.

We fabricate solar cells from an active layer blend of PDPP5T:IEICO-4F and extensively analyze them using a range of spectral techniques (PL/EL/Abs/SubbandGap-EQE). Then we correct the recorded spectra for suppression or enhancement of the absorption or luminescence as a consequence of thin-film cavity effects. With these corrected spectra in hand, and with the help of morphological analysis tools like TEM/AFM/2D-GIWAXS, we aim to explain the change in device characteristics upon changing the solvent system.

Results regarding the efficiency look promising with over 50% EQE improvement using a ternary solvent system. This solvent system is comprised of chloroform and 1,8-diiodooctane with varying concentrations of chlorobenzene. Current results suggest that the addition of chlorobenzene to the mixture increased stacking efficiency in the IEICO-4F phase, which was reflected in 2D-GIWAXS and the (interference corrected) spectral data, and that this better packing has led to the increase in EQE and the decrease Voc.

© FUNDACIO DE LA COMUNITAT VALENCIANA SCITO
We use our own and third party cookies for analysing and measuring usage of our website to improve our services. If you continue browsing, we consider accepting its use. You can check our Cookies Policy in which you will also find how to configure your web browser for the use of cookies. More info