Publication date: 7th February 2022
Magnetoelectric (ME) composites offer strain-mediated coupling between the ferroelectric matrix and ferromagnetic filler. They also find their application in magnetic field sensors, energy harvesters, and biomedicine.[1, 2] The requirement of flexible devices with the advent of the internet of things (IoT) and Industry 4.0 has increased. Therefore, we report a co-polymer polyvinylidene fluoride-trifluoroethylene P(VDF-TrFE) based ME composite here. Reduced functional properties are often a case for ME polymeric composites due to the magnetic filler's low resistivity and the formation of long-range conducting paths.[3-5] As a remedy, we fabricated a dual-phase magnetic filler having magnesium hydroxide Mg(OH)2 nanoplates acted as template material for localized growth of Fe3O4 nanoparticles on the template surface during a single-pot hydrothermal reaction. The optimized spin-coated film MFPT5 has filler loading of 5wt%, and we obtained an enhanced ferroelectric polarization value for MFPT5 than that of the pristine film, MFPT0. The leakage current was reduced, and the crystallinity of the MFPT5 film was also increased. Therefore, the work discussed here paves the way to develop ME composites with low leakage current to obtain a multifunctional material. Finally, we characterized the magnetic behavior of MFPT5 films and exploited them for triboelectric nanogenerator (TENG) application and detection of stray magnetic fields of electrical appliances. Thus, the proposed ME sensor can assure the safety of working personnel at industries by detecting the magnetic field of heavy machinery and sending a signal to their wearable devices.
•Science and Engineering Research Board of the Department of Science and Technology, Government of India for the financial support through an IMPRINT-II Grant (IMP/2018/001703).
•The organizers of the conference.
•Thesis supervisors