Lead-Free Perovskites for Optoelectronics
Isabella Poli a
a Istituto Italiano di Tecnologia Via Morego 30, 16163 Genova, Italy
Proceedings of MATSUS Fall 2026 Conference (MATSUSFall26)
A1 Beyond Efficiency: Perovskite Optoelectronics for Scalable and Stable Devices
Palma, Spain, 2026 October 26th - 30th
Organizers: Guixiang Li and Silver-Hamill Turren-Cruz
Invited Speaker, Isabella Poli, presentation 008
Publication date: 22nd July 2026

As metal halide perovskites approach technological maturity, the research is now shifting from record-breaking efficiencies toward stability, scalability, and environmental sustainability. While lead-based perovskites currently hold the highest performance in photovoltaics, lead-free alternatives are rapidly emerging, offering not only reduced toxicity but also distinctive optoelectronic properties. In this talk, I will present recent advances spanning from tin-based three-dimensional perovskites to bismuth halide-based compositions, highlighting how compositional and structural diversity can be exploited to target a broad range of optoelectronic applications. Particular attention will be devoted to the relationship between composition, defect physics, and stability. Tin-based perovskites enable narrower bandgaps suitable for infrared absorption and tandem applications, while low-dimensional bismuth-based compounds exhibit broadband visible emission arising from their localized electronic states. These features open new opportunities that extend beyond the capabilities of conventional lead-based materials. Beyond materials design, the talk will also emphasize the development of scalable and green processing strategies. I will discuss approaches ranging from mechanochemical synthesis of perovskite powders to the deposition of thin films via slot-die coating, demonstrating pathways toward industrially relevant fabrication while avoiding the use of toxic solvents. By integrating advances in materials chemistry with sustainable manufacturing, this talk reviews the development of stable, scalable, and environmentally friendly perovskite technologies.

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