Single Perovskite Quantum Dots as Room-Temperature Quantum Emitters and Photochemical Reporters
Maksym Kovalenko a b
a ETH Zurich, Laboratory of Inorganic Chemistry, Department of Chemistry & Applied Biosciences, Vladimir-Prelog-Weg, 1, Zürich, Switzerland
b Empa-Swiss Federal Laboratories for Materials Science and Technology, Dübendorf, 8600, Switzerland
Proceedings of MATSUS Fall 2026 Conference (MATSUSFall26)
B4 Fundamental Understanding of Halide Perovskite Materials, Interfaces and Devices
Palma, Spain, 2026 October 26th - 30th
Organizers: Krishanu Dey and Sudipta Seth
Invited Speaker, Maksym Kovalenko, presentation 040
Publication date: 22nd July 2026

Lead halide perovskite nanocrystals (LHP NCs) [1] - the latest generation of colloidal quantum dots (QDs) - possess dynamic, entropically stabilized soft lattices and electronically benign surfaces that, remarkably, do not compromise their textbook semiconductor optical quality. The compositional diversity of APbX3 comprises cesium ions on A-site as the only ones forming fully inorganic perovskite lattice of this kind, whereas a range of organic cations readily form this lattice, methylammonium (MA), formamidinium (FA), aziridinium (AZ) [2-4]. The surface chemistry of perovskite QDs is paramount for instilling (photo)chemical stability. We will review four distinct cases of capping ligands, based on their binding tightness and dynamicity, emphasizing synthetic phospholipids as the best-performing [5]. Structurally dynamic FA/MA/AZ-based QDs, stabilized with zwitterions, turned out to be near-perfect (blinking free, saturable, high single-photon purity) single-photon sources (incoherent) at room temperatures [6], as attributed to the dynamic wavefunction localization. Beyond photophysics, LHP QDs have recently proven to be efficient photocatalysts, mediating organic redox transformations that remain inaccessible to conventional photocatalysts [7], and which properties are governed by the dynamic surface-ligand interface [8]. We then demonstrate observation of a single photocatalyst via micro-photoluminescence measurements of its single-photon emission [9], addressing static and temporal heterogeneity in photocatalytic function. The presentation will summarize the contributions of my interdisciplinary team and our international collaborators, whose names will be acknowledged in the presentation and accompanying notes.

 

 

1. L. Protesescu et al. Nano letters 2015, 15, 3692–3696

2. Q. Akkermann et al. Science, 2022, 377, 1406-1412

3. V. Morad et al. J. Am. Chem. Soc., 2025, 147, 8, 6795–6804

4. M. Bodnarchuk et al. ACS Nano, 2024, 18, 7, 5684–5697

5. V. Morad et al. Nature, 2024, 626, 542–548

6. L. Feld et al. Nature Comm., 2026, 17, 1974.

7. V. M. Amberg et al. J. Am. Chem. Soc., 2025, 147, 10, 8548–8558

8. Y. Sahin et al. Nano Lett., 2026, 26, 9, 3107–3116

9. L. Feld et al. 2026 in revision, https://doi.org/10.26434/chemrxiv.10001851/v1

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