Multi-Interface Engineering and Evolutionary Dynamics in Perovskite Photovoltaics: From Fundamental Charge Carrier Control to Scalable Devices
Mojtaba Abdi Jalebi a
a Institute for Materials Discovery, University College London, Malet Place, London WC1E 7JE, UK
Proceedings of MATSUS Fall 2026 Conference (MATSUSFall26)
A5 Interface Engineering, Optical Strategies and Multijunction Designs in Perovskite Photovoltaics and Optoelectronics
Palma, Spain, 2026 October 26th - 30th
Organizers: Clara Aranda Alonso and Monika Rai
Invited Speaker, Mojtaba Abdi Jalebi, presentation 165
Publication date: 22nd July 2026

The commercial deployment of metal halide perovskite photovoltaics hinges on bridging the gap between small-scale laboratory efficiencies and long-term operational stability at an industrial scale. Physical and chemical interfaces within these device architectures represent critical bottlenecks, governing non-radiative recombination, ion migration, and energetic misalignment. This talk presents a comprehensive approach to mastering these boundaries by controlling the buried heterojunction, understanding long-term surface evolution, and deploying multimodal strategies for scalable optoelectronic applications. First, we address the buried interface by introducing a multifunctional polymer matrix (sodium hyaluronate) to disperse SnO2 nanoparticles. This approach yields highly uniform, strain-relaxed perovskite films with eliminated oxygen vacancies, achieving a champion power conversion efficiency (PCE) of 25.11% and excellent ambient stability[1]. Second, we explore the dynamic nature of 2D/3D surface heterojunctions under long-term operation. We systematically trace the evolution of charge carrier dynamics as these interfaces age, demonstrating that controlled phase changes and the emergence of PbI2 crystals can naturally optimize interfacial band alignment, boosting the open-circuit voltage from 1.14 V to 1.18 V[2]. Finally, we translate these fundamental interface insights into functional, scalable technologies. By combining transfer matrix optical modeling with targeted molecular passivation (using 3-trifluoromethyl-1H-1,2,4-triazole), we overcome the transparency-efficiency trade-off in semi-transparent perovskite solar cells for building-integrated photovoltaics and indoor electronics. This framework achieves a record indoor PCE of 22.41% under 1000 lux illumination and successfully scales to a 30 x 30 cm2 semi-transparent module [3]. Together, these interlinked interfacial strategies provide a clear, industrially compatible roadmap toward highly stable, next-generation perovskite technologies.

M. Abdi-Jalebi gratefully acknowledges the funding received from the European Union's Horizon Europe research and innovation program for the SUNPEROM project (grant agreement no. 101223212). M. Abdi-Jalebi acknowledges University College London's (UCL) Research, Innovation and Global Engagement Fund and the UCL – Korea University Strategic Partner Fund for their financial support.

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