Kinetic Control of Polytypism in Formamidinium Lead Halide Perovskites
Nakita K. Noel a
a Clarendon Laboratory, Department of Physics, University of Oxford, Oxford, United Kingdom.
Proceedings of MATSUS Fall 2026 Conference (MATSUSFall26)
A4 Pathways to Stable Metal Halide Perovskites
Palma, Spain, 2026 October 26th - 30th
Organizers: Oussama ER-RAJI and Mostafa Othman
Invited Speaker, Nakita K. Noel, presentation 296
Publication date: 22nd July 2026

Formamidinium-based metal halide perovskites have emerged as leading candidates for next-generation photovoltaic technologies due to their exceptional optoelectronic properties and compositional tunability, allowing them to be applied to both single- and multijunction devices. Despite this progress, their rich structural landscape presents significant challenges, with multiple competing crystalline phases often coexisting in device-relevant thin films, where the presence of the lower symmetry polymorphs is often regarded as detrimental to device performance.

In this presentation, I will discuss our recent work exploring the relationship between crystal structure and optoelectronic behaviour in FA-based perovskites. In particular, I will demonstrate how composition and crystallisation kinetics can be used to manipulate structural complexity, providing new insight into the origin of unusual optical signatures that have recently been linked to reduced photovoltaic performance. I will also present emerging strategies for controlling phase formation across challenging compositional regimes, highlighting opportunities to both suppress performance-limiting structural motifs and exploit them to access new nanoscale optoelectronic phenomena. Overall, these investigations demonstrate how understanding and controlling polymorphism provides a powerful framework for engineering the structure–property relationships of metal halide perovskites, with potential implications extending beyond photovoltaics to emerging quantum and photonic applications.

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