Publication date: 22nd July 2026
Exsolution involves redox precipitation of metal nanoparticles from metal oxides, resulting in materials that exhibit excellent electrocatalytic properties and hold great promise for novel types of nanoscale heterostructures. Exsolution is described by three point defect equations involving the reduction of the host oxide, reduction and exsolution of the transition metal, and annihilation of host unit cells. Guided by their predictions, significantly enhanced exsolution in terms of molar amount, rate, and nucleation density is achieved by acceptor substitution to the system La0.2Ca0.7Ti0.95Cu0.05O3−δ through atomic scale imaging and in situ X-ray diffraction and spectroscopy [1]. Moreover, multiple stages of exsolution are deconvoluted with increasing thermal activation: 1) minor exsolution of anchored surface nanoparticles, 2) exsolution of endoparticles within the bulk, and 3) diffusion and coalescing in the bulk and at the surfaces [2]. Strain in both the host oxide and the exsolved metal can constitute an additional thermodynamic barrier for exsolution beyond the availability of the required point defects.
The Research Council of Norway (RCN) is acknowledged for support of the Norwegian Centre for Transmission Electron Microscopy (NORTEM, project no. 197405) and the Swiss-Norwegian beamlines at ESRF (project no. 296087). The authors acknowledge the ESRF for provision of synchrotron radiation facilities under proposal number A31-1-270 and MA-6848, and we would like to thank Wouter van Beek and Kenneth Marshall for assistance and support in using beamline BM31.
