Transparent Conducting Oxides: A Lever for Efficiency and Stability in Perovskite–Silicon Tandem Solar Cells
Monica Morales Masis a
a Materials to Optoelectronic Devices (M2D) & Institute for Complex Molecular Systems, Eindhoven University of Technology (TU/e), P.O. Box 513, 5600 MB Eindhoven, The Netherlands
Proceedings of MATSUS Fall 2026 Conference (MATSUSFall26)
A4 Pathways to Stable Metal Halide Perovskites
Palma, Spain, 2026 October 26th - 30th
Organizers: Oussama ER-RAJI and Mostafa Othman
Invited Speaker, Monica Morales Masis, presentation 373
Publication date: 22nd July 2026

Transparent Conducting Oxides (TCOs) sit at nearly every critical interface in perovskite–silicon tandem solar cells, governing optical coupling, charge extraction, and recombination, while introducing resistive, absorptive, and reflective losses that can each cost more than 2% absolute efficiency.

Beyond performance, TCO choice and quality can directly affect long-term device stability: microstructure and interfacial chemistry determine resistance to moisture ingress, ion migration, and damp-heat degradation, factors that are too often considered separately from efficiency optimization. In this talk, I will argue that TCOs deserve treatment as an important design parameter, alongside the carrier extraction and perovskite absorber itself, in the pursuit of tandem cells that are both highly efficient and operationally durable. I will discuss the materials physics trade-offs involved, current material limitations including reliance on scarce indium-based oxides, and emerging strategies (new dopants, multilayer architectures, and computational screening) aimed at simultaneously improving optoelectronic performance and long-term stability for sustainable deployment.

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