Publication date: 22nd July 2026
Single-atom catalysts (SACs) are highly attractive for catalytic water splitting due to their ability to maximize the utilization efficiency of metal atoms. In this work, copper single atoms (CuSACs) were heterogeneously anchored onto the MWCNT/FeMOF (CuSACs@MC/FM) catalyst surface through atomic-level dispersion of Cu, effectively tuning the heterogeneity of the catalyst. The existence of CuSACs enhances the number of accessible active sites, enabling efficient hydrogen and oxygen evolution reaction (HER and OER) activity in alkaline media. The CuSACs@MC/FM hybrid catalysts exhibit low overpotentials, small Tafel slope value and excellent durability of up to 100 h for both OER and HER. Furthermore, we assembled a bifunctional CuSACs@MC/FM hybrid catalyst for overall water splitting and achieved a low cell voltage of 1.54 V at 10 mA/cm2 with excellent long-term stability. Additionally, CuSACs@MC/FM delivered a high mass activity of 70 A/g and ~84 % selectivity for H2O2 in the ORR. X-ray absorption spectroscopy revealed a dominant Cu–N coordination peak at ~1.4 Å, confirming the presence of atomically dispersed Cu–N sites that serve as the active centers and enhance the heterogeneous catalytic activity. This work demonstrates that interfacial site tuning and atomic-level modulation can significantly improve catalyst durability and efficiency, establishing CuSACs@MC/FM as a highly effective electrocatalyst to produce both H2 and H2O2.
This research was supported by Basic Science Research Program through the National Research Foundation of Korea(NRF) funded by the Ministry of Education of KOREA (No. RS-2021-NR060117).
