One-Pot Synthesis of Quasi 2D/3D Perovskite Based Heterostructure for Enhanced X-ray Detection: Breaking the Sensitivity Dark Current Trade-Off
Singh Rajveer a, Elke Debroye a
a Department of Chemistry, KU Leuven, BE, Celestijnenlaan, 200F, Leuven, Belgium
Proceedings of MATSUS Fall 2026 Conference (MATSUSFall26)
B4 Fundamental Understanding of Halide Perovskite Materials, Interfaces and Devices
Palma, Spain, 2026 October 26th - 30th
Organizers: Krishanu Dey and Sudipta Seth
Poster, Singh Rajveer, 503
Publication date: 22nd July 2026

Exposure to high doses of X-rays in medical imaging poses significant health risks due to their high photon energy and deep skin penetration, necessitating the development of highly sensitive detectors capable of operating at lower radiation doses. Perovskite materials have emerged as promising candidates for X-ray detection, with research evolving from organic systems (e.g., CH₃NH₃PbBr₃) to inorganic counterparts (CsPbBr₃) owing to their superior photo-, thermal-, and moisture stability1. However, challenges such as material instability and high dark current continue to limit their practical application2.

Low-dimensional perovskites, particularly quasi-2D structures composed of inorganic slabs separated by organic cations, offer enhanced structural stability. Nevertheless, they often suffer from limited charge transport and reduced sensitivity. To address these limitations, semiconductor heterostructure engineering has emerged as an effective strategy, combining the advantages of different components to improve charge separation and transport while suppressing undesirable effects such as dark current3.

In this work, we report the synthesis of PEA2Cs2Pb3Br10/CsPbBr3 perovskite heterostructure microcrystals (~20–40 μm) and their structural and optical characterization4. Their charge carrier behaviour at the interface is investigated upon chemically connecting the two phases. Further their potential for X-ray detectors is demonstrated through proof-of-concept X-ray detector devices.

Compared to their individual constituents, the heterostructures achieve a high sensitivity of 13488.57 μC/Gycm2 and a low limit of detection of 18 μGy/s. This improvement is attributed to more efficient charge-carrier seperation at the heterointerface and suppressed ion migration.

These results highlight quasi-2D/3D perovskite heterostructures as promising candidates for next-generation, high-performance X-ray detectors

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