Publication date: 16th July 2025
The halide perovskite solar cell absorbers require an appropriate band gap, high light absorption, high charge carrier mobility, long charge carrier lifetime and a work function that matches available selective transport layers. In this presentation we will discuss the different contributions of the constituents of the respective crystal to the dielectric constant of the absorber material. The dielectric response strongly affects the charge carrier lifetime and the screening of defect states. We will consider a number of materials and our understanding of the effects six years ago and now. Cases of 3D, 2D, 1D and 0D octahedra connectivities will be compared. New molecular cations will be incorporated. The apparent conflict between the terminology of dielectric and ferroelectric effects will be consolidated. The influence of unpaired electrons in heavy ions and the dynamics of the molecular cations will be compared. Structural phase transitions associated with ordering processes will be discussed.
The authors acknowledge funding through the Deutsche Forschungsgemeinschaft via the project 424708448. Discussions with Astita Dubey, Marianela Escobar Castillo, Vladimir Shvartsman, Hassan Esmaili, Boris Slautin, Sobhan Fathabad, Bernd Marler, and Andrei Salak are greatly acknowledged. W.A. acknowledges funding through the Office of Educational Affairs of the Government of Thailand.